Product ID:MS-143 FLUOROCARBON RELEASE AGENT
MSDS Date:01/01/1990
FSC:9150
NIIN:01-078-9586
MSDS Number: BMWYF

MILLER-STEPHENSON CHEMICAL CO INC.

GEORGE WASHINGTON HIGHWAY
DANBURY, CT 06810
US

Emergency Phone: 203-797-2212 OR 800-424-9300

Info Phone: 203-743-4447

Cage: 18598

MILLER-STEPHENSON CHEMICAL CO INC

950 DANBURY, CT 06810 US

Telephone: 203-743-4447

Cage: 18598

1,1,2-TRICHLORO-1,2,2-TRIFLUOROETHANE (FREON 113) (SARA

CAS: 76-13-1

RTECS: KJ4000000

Fraction By Weight: 97%

OSHA PEL 1000PPM/1250STEL

ACGIH TLV: 1000PPM/1250STEL9192

TELOMERS OF TETRAFLUOROETHYLENE

CAS: 79070-11-4

Fraction By Weight: 3%

Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:INHALATION-VAPORS ARE HEAVIER THAN AIR
& CAN REDUCE OXYGEN FOR BREATHING. EXCESSIVE INHALATION OF
PYROLIZED FUMES VAN CAUSE FLU LIKE "POLYMER FUME FEVER".
SKIN-CONTACT WILL RESULT IN IRRITATION. EYE-C ONTACT WILL CAUSE
IRRITATION. ORAL-ALTHOUGH ORAL TOXICITY IS LOW, INGESTION IS TO BE
AVOIDED.
Explanation of Carcinogenicity:THIS COMPOUND CONTAINS NO INGREDIENTS AT
CONCENTRATIONS OF 0.1% OR GREATER THAT ARE CARCINOGENS OR SUSPECT
CARCINOGENS.
Effects of Overexposure:INHALATION-EXCESSIVE INHALATION CAN CAUSE
DIZZINESS, NARCOSIS, ANESTHIA, CARDIAC IRREGULARITIES,
UNCONSCIOUSNESS OR DEATH. SKIN-CONTACT WILL CAUSE DEFATTING OF THE
SKIN.
Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISEASE.

First Aid:INHALATION-REMOVE TO FRESH AIR. IF NEEDED, PERFORM CPR OR
GIVE OXYGEN. DO NOT GIVE EPINEPHRINE OR SIMILAR DRUGS AS SUCH DRUGS
MAY INDUCE VENTRICULAR ARRHYTHMIA. EYES-FLUSH EYE WITH PLENTY OF
WATER AT LEAST 15 MIN. CONTACT PHYSICIAN. SKIN-FLUSH WITH WATER.
SEE PHYSICIAN IF IRRITATION IS PRESENT. ORAL-DO NOT INDUCE
VOMITING. GIVE TWO GLASSES OF WATER OR ACTIVATED CHARCOAL SLURRY.

Flash Point Method:TOC
Flash Point:NONE
Extinguishing Media:"ALCOHOL" FOAM. DRY POWDER (SAND OR MET-L-X),
CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:EVACUATE PERSONNEL TO SAFE AREA. DECOMPOSITION
MAY FORM TOXIC COMPOUNDS. SELF CONTAINED BREATHING APPARATUS MAY BE
REQUIRED IF DRUM RUPTURE & CONTENTS SPILLS.
Unusual Fire/Explosion Hazard:DRUMS MAY RUPTURE UNDER FIRE.
DECOMPOSITION MAY OCCUR. AIR-BORNE SOLID PARTICLES MAY BE GENERATED
ABOVE 216C. AT 260-290C FORMS TOXIC FLUORINE COMPOUNDS.

Spill Release Procedures:VENTILATE AREA. VAPORS TEND TO CONCENTRATE IN
LOW AREAS. REVIEW FIRE & EXPLOSION HAZARD & SAFETY PRECAUTIONS
BEFORE PROCEEDING WITH CLEAN UP. WIPE UP SPILL WITH ABSORBENT
MATERIAL & DISPOSE TO LANDFIL L. WASH HANDS WITH SOAP & WATER.

Handling and Storage Precautions:DO NOT STORE NEAR SOURCES OF HEAT
ABOVE 125F/52C. DO NOT STORE OR CONSUME FOOD, DRINK OR TOBACCO IN
AREA WHERE IT HAS BECOME CONTAMINATED WITH PRODUCT
Other Precautions:HANDLING-FREEZING WILL AFFECT THE PHYSICAL CONDITION
BUT WILL NOT DAMAGE. THAW & MIX BEFORE USING. ROTATE STOCK TO SHELF
LIFE OF 1 YEAR**TO PREPARE SLURRY, SUSPEND 50 G ACTIVATED CHARCOAL
IN 400 ML WA TER. SHAKE, GIVE 5 ML/KG OR 260 ML.

Respiratory Protection:NONE SPECIFIED BY MANUFACTURER.
Ventilation:USE LOCAL EXHAUST, IF LARGE AMOUNTS ARE RELEASED.
MECHANICAL VENTILATION SHOULD BE USED IN LOW PLACES.
Protective Gloves:VINYL OR NEOPRENE GLOVES
Eye Protection:CHEMICAL SPLASH GOGGLES
Other Protective Equipment:PRUDENT USAGE WOULD NOT REQUIRE EYE AND SKIN
PROTECTION.
Work Hygienic Practices:DO NOT CONSUME FOOD, DRINK OR TOBACCO IN AREAS
WHERE THEY MAY BECOME CONTAMINATED WITH THIS MATERIAL.
Supplemental Safety and Health
NOTE TO PHYSICIAN: BECAUSE OF A POSSIBLE INCREASED RISK OF ELICITING
CARDIAC DYSRYTHMIAS, CATECHOLAMINE DRUGS, SUCH AS EPINEPHRINE,
SHOULD BE CONSIDERED ONLY AS A LAST RESORT IN LIFE THREATENING
EMERG ENCIES.

HCC:T6
Boiling Pt:=47.8C, 118.F
Vapor Pres:334 MMHG
Vapor Density:2.9 @77F
Spec Gravity:1.6
pH:7
Evaporation Rate & Reference:1 (N-BUTYL ACETATE=1)
Solubility in Water:NEGLIGIBLE
Appearance and Odor:FORM: DISPERSION. COLOR: WHITE. APPERANCE: MILKY.
ODOR: FAINT SOLVENT.
Percent Volatiles by Volume:97%

Stability Indicator/Materials to Avoid:YES
FINELY DIVIDED REACTIVE METALS.
Stability Condition to Avoid:DO NOT USE NEAR OPEN FLAMES OR RED HOT
SURFACES. DO NOT SMOKE WITH CONTAIMNATED TOBACCO OR HANDS.
Hazardous Decomposition Products:INTENSE HEAT MAY CAUSE DECOMPOSITION
WITH EMISSION OF HALOGEN ACIDS, PHOSGENE IN SMALLER AMOUNTS &
PERFLUOROCARBONS.

Waste Disposal Methods:RECLAIM SOLOVENT BY FILTRATION & DISTILLATION.
DO NOT FLUSH TO SURFACE WATER OR SEWER SYSTEM. DISPOSAL SERVICE TO
LANDFILL IS APPROPIATE AS FEDERAL, STATE AND LOCAL REGULATIONS
PERMIT. CONSULT LOCAL W ASTE DISPOSAL CONTRACTOR. DO NOT BURN.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.